Ground-and Excited-State Dipole Moments and Oscillator Strengths of Full Configuration Interaction Quality - Archive ouverte HAL Access content directly
Journal Articles Journal of Chemical Theory and Computation Year : 2023

Ground-and Excited-State Dipole Moments and Oscillator Strengths of Full Configuration Interaction Quality

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Abstract

We report ground- and excited-state dipole moments and oscillator strengths (computed in different ``gauges'' or representations) of full configuration interaction (FCI) quality using the selected configuration interaction method known as \textit{Configuration Interaction using a Perturbative Selection made Iteratively} (CIPSI). Thanks to a set encompassing 35 ground- and excited-state properties computed in 11 small molecules, the present near-FCI estimates allow us to assess the accuracy of high-order coupled-cluster (CC) calculations including up to quadruple excitations. In particular, we show that incrementing the excitation degree of the CC expansion (from CCSD to CCSDT or from CCSDT to CCSDTQ) reduces the average error with respect to the near-FCI reference values by approximately one order of magnitude.
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Dates and versions

hal-03844802 , version 1 (09-11-2022)

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Yann Damour, Raúl Quintero-Monsebaiz, Michel Caffarel, Denis Jacquemin, Fábris Kossoski, et al.. Ground-and Excited-State Dipole Moments and Oscillator Strengths of Full Configuration Interaction Quality. Journal of Chemical Theory and Computation, 2023, 19 (1), pp.221-234. ⟨10.1021/acs.jctc.2c01111⟩. ⟨hal-03844802⟩
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