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Journal articles
Carbohydrate Self-Assembly at Surfaces: STM Imaging of Sucrose Conformation and Ordering on Cu(100)
Sabine Abb
1
Nathalie Tarrat
2
Juan Cortés
3
Bohdan Andriyevsky
4
Ludger Harnau
J. Christian Schön
1
Stephan Rauschenbach
1, 5
Klaus Kern
1, 6
2
CEMES-SINanO - Surfaces, Interfaces et Nano-Objets
CEMES - Centre d'élaboration de matériaux et d'études structurales
3
LAAS-RIS - Équipe Robotique et InteractionS
LAAS - Laboratoire d'analyse et d'architecture des systèmes
Sabine Abb 1
Author
Nathalie Tarrat 2
Mail :
Author IdHAL : nathalie-tarrat
Juan Cortés 3
Mail : Site :
Author Employer institution : Équipe Robotique et InteractionS IdHAL : juan-cortes ResearcherId : http://www.researcherid.com/rid/F-7545-2019 ORCID : https://orcid.org/0000-0002-4660-0306
Bohdan Andriyevsky 4
Author
Ludger Harnau
Mail :
Author
J. Christian Schön 1
Author
Stephan Rauschenbach 1, 5
Author
Klaus Kern 1, 6
Author
1
Max Planck Institute for Solid State Research (Heisenbergstraße 1 - 70569 Stuttgart - Germany)
- Max-Planck-Gesellschaft (Jägerstrasse, 10-11, D-10117 Berlin - Germany)
2
CEMES-SINanO - Surfaces, Interfaces et Nano-Objets (CEMES 29 rue Jeanne Marvig, BP 94347, F-31055 Toulouse Cedex 4 - France)
- CEMES - Centre d'élaboration de matériaux et d'études structurales (29 Rue Jeanne Marvig - BP 94347 31055 TOULOUSE CEDEX 4
- France)
- INSA Toulouse - Institut National des Sciences Appliquées - Toulouse (135, avenue de Rangueil - 31077 Toulouse cedex 4 - France)
- ICT-FR 2599 - Institut de Chimie de Toulouse (118 Route de Narbonne 31062 Toulouse cédex 9 - France)
- IRD - Institut de Recherche pour le Développement (Siège Le Sextant 44, bd de Dunkerque CS 90009 13572 Marseille cedex 02 - France)
- UT3 - Université Toulouse III - Paul Sabatier (118 route de Narbonne - 31062 Toulouse - France)
- Université Fédérale Toulouse Midi-Pyrénées (41 Allée Jules Guesde, 31000 Toulouse - France)
- CNRS - Centre National de la Recherche Scientifique : FR2599 (France)
- Toulouse INP - Institut National Polytechnique (Toulouse) (France)
- Université Fédérale Toulouse Midi-Pyrénées (41 Allée Jules Guesde, 31000 Toulouse - France)
- UT3 - Université Toulouse III - Paul Sabatier (118 route de Narbonne - 31062 Toulouse - France)
- Université Fédérale Toulouse Midi-Pyrénées (41 Allée Jules Guesde, 31000 Toulouse - France)
- CNRS - Centre National de la Recherche Scientifique : UPR8011 (France)
3
LAAS-RIS - Équipe Robotique et InteractionS ( - France)
- LAAS - Laboratoire d'analyse et d'architecture des systèmes (7 Av du colonel Roche 31077 TOULOUSE CEDEX 4 - France)
- Toulouse INP - Institut National Polytechnique (Toulouse) (France)
- Université Fédérale Toulouse Midi-Pyrénées (41 Allée Jules Guesde, 31000 Toulouse - France)
- INSA Toulouse - Institut National des Sciences Appliquées - Toulouse (135, avenue de Rangueil - 31077 Toulouse cedex 4 - France)
- UT3 - Université Toulouse III - Paul Sabatier (118 route de Narbonne - 31062 Toulouse - France)
- Université Fédérale Toulouse Midi-Pyrénées (41 Allée Jules Guesde, 31000 Toulouse - France)
- CNRS - Centre National de la Recherche Scientifique : UPR8001 (France)
- UT1 - Université Toulouse 1 Capitole (2 rue du Doyen-Gabriel-Marty - 31042 Toulouse Cedex 9 - France)
- UT2J - Université Toulouse - Jean Jaurès (5 allées Antonio Machado - 31058 Toulouse Cedex 9 - France)
- Toulouse INP - Institut National Polytechnique (Toulouse) (France)
4
Koszalin University of Technology (Poland)
5
Department of Chemistry, University of Oxford (12 Mansfield Road, Oxford OX1 3TA - United Kingdom)
- University of Oxford [Oxford] (Wellington Square, Oxford OX1 2JD - United Kingdom)
- Chemistry Research Laboratory (France)
6
Institut de Physique [Lausanne] (EPSL, CH-1015 Lausanne - Switzerland)
- EPFL - Ecole Polytechnique Fédérale de Lausanne (CH-1015 Lausanne, Switzerland - Switzerland)
Abstract : Saccharides are ubiquitous biomolecules but little is known about their interaction with and assembly at surfaces. Combining preparative mass spectrometry with scanning tunneling microscopy, we have been able to address the conformation and self-assembly of the disaccharide sucrose on the Cu(100) surface with subunit-level imaging. By combining a multi-stage modelling approach and experimental data, we can rationalize the conformation on the surface as well as the interactions between the sucrose molecules, yielding models of the observed self-assembled patterns on the surface.
Document type :
Journal articles
Domain :
Complete list of metadatas
https://hal.laas.fr/hal-02146428
Contributor : Juan Cortés <>
Submitted on : Monday, June 3, 2019 - 11:22:37 PM
Last modification on : Monday, January 13, 2020 - 1:13:10 AM
Contributor : Juan Cortés <>
Submitted on : Monday, June 3, 2019 - 11:22:37 PM
Last modification on : Monday, January 13, 2020 - 1:13:10 AM
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Identifiers
- HAL Id : hal-02146428, version 1
- DOI : 10.1002/anie.201901340
Collections
LAAS | UNIV-TLSE3 | CNRS | SINANO | CEMES | INSA-TOULOUSE | LAAS-ROBOTIQUE | LAAS-RIS | INSA-GROUPE | UT1-CAPITOLE | UNIV-TLSE2 | IRD | INC-CNRS | TDS-MACS
Citation
Sabine Abb, Nathalie Tarrat, Juan Cortés, Bohdan Andriyevsky, Ludger Harnau, et al.. Carbohydrate Self-Assembly at Surfaces: STM Imaging of Sucrose Conformation and Ordering on Cu(100). Angewandte Chemie International Edition, Wiley-VCH Verlag, 2019, 58 (25), pp.8336-8340. ⟨10.1002/anie.201901340⟩. ⟨hal-02146428⟩
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